作者单位
摘要
1 合成与天然功能分子教育部重点实验室,西北大学化学与材料科学学院,陕西 西安 710127
2 西安石油大学化学化工学院,陕西 西安 710065
钪(Sc)被广泛用于固体氧化燃料电池、陶瓷材料、催化剂与轻质高温合金等的制造,是不可或缺的重要战略资源,稀土矿石中Sc元素的定量分析对于稀土矿的勘探、开采具有重要意义。笔者提出了一种基于激光诱导击穿光谱(LIBS)结合随机森林(RF)算法的稀土矿石样品中Sc元素定量分析的方法。首先,考察了不同光谱预处理方法对RF校正模型预测性能的影响;然后,利用变量重要性测量(VIM)进行RF校正模型输入变量的选择与优化。为了进一步验证VIM-RF模型的预测性能,将其与标准曲线法、偏最小二乘(PLS)以及基于波段选择的RF模型进行了比较。最后,在最优化的光谱预处理(WT)和VIM阈值(阈值为0.016)等条件下,建立了基于小波变换结合VIM的RF校正模型。结果表明,VIM-RF校正模型表现出了良好的预测性能:RCV2为0.9981,RMSECV为0.0430 mg/kg,MRECV为0.0047,RP2为0.9993,RMSEP为0.4964 mg/kg,MREP为0.0481。因此,LIBS技术结合RF算法可以有效实现稀土矿石中稀土元素Sc的定量分析,可为稀土矿石的品位分析与精准开采提供借鉴。
光谱学 激光诱导击穿光谱 稀土矿石 定量分析 随机森林 变量选择 
中国激光
2024, 51(2): 0211001
作者单位
摘要
1 西安石油大学化学化工学院, 陕西 西安 710065
2 西北大学化学与材料科学学院, 陕西 西安 710127
3 西安石油大学化学化工学院, 陕西 西安 710065 西北大学化学与材料科学学院, 陕西 西安 710127
正丁醇具有互溶性好、 挥发性低、 价格低廉以及腐蚀性低等优势, 被认为是理想的柴油添加物。 柴油中正丁醇的精准定量分析对其品质快速评价与市场监督具有重要科学意义与实用价值。 提出了一种基于拉曼(Raman)光谱结合偏最小二乘(PLS)的柴油中正丁醇快速定量分析方法。 首先, 采集了40个柴油样品的Raman光谱, 并考察了不同预处理方法[一阶导数、 二阶导数、 多元散射校正、 标准正态变换、 归一化(Normalization)和小波变换]对PLS校正模型预测性能的影响; 其次, 采用变量重要性投影(VIP)对Normalization方法预处理后的光谱数据进行特征变量提取, 并采用五折交叉验证优化VIP的阈值; 最后, 基于最优的光谱预处理方法、 输入变量和模型参数, 构建PLS校正模型对柴油中正丁醇含量进行快速定量分析, 结果与基于原始光谱(RAW)和Normalization光谱的PLS校正模型的预测性能进行对比。 结果表明: Normalization-VIP-PLS校正模型展现出优异的预测能力(R2CV和RMSECV为0.998 4和0.236 2%: R2P和RMSEP为0.998 7和0.208 4%; RSD为0.035 5)。 成功建立了一种Raman光谱结合PLS算法的柴油中正丁醇快速定量分析方法, 该方法具有快速、 准确、 便捷等优势, 可为柴油以及其他燃料中添加物检测及其品质分析提供新思路与新方法。
拉曼光谱 偏最小二乘 柴油 添加剂 Raman spectroscopy Partial least squares Diesel Additive 
光谱学与光谱分析
2023, 43(7): 2153
作者单位
摘要
1 中铁十八局集团第二工程有限公司,唐山 063000
2 北京科技大学土木与资源工程学院,北京 100083
3 中国铁道科学研究院,研究生部,北京 100081
4 中国铁道科学研究院集团有限公司,高速铁路轨道技术国家重点实验室,北京 100081
针对高原地区桥墩混凝土服役环境的特点,探究矿物掺合料对桥墩混凝土性能的影响效果。采用Box-Behnken Design响应面法(RSM-BBD)设计了15组试验,详细研究了粉煤灰、矿渣和硅灰掺量对混凝土强度和冻融性能的影响规律。以28 d抗压强度、200次冻融循环后混凝土质量损失率和相对动弹性模量为响应值构建响应面模型,旨在揭示响应参数和目标响应值的相关关系及多目标响应值条件下桥墩混凝土的合理配合比。结果表明,与基准组混凝土相比,适量的矿物掺合料有利于提高混凝土强度,增强混凝土的耐低温冻融性能。混凝土的强度和抗冻融性能主要受单因素的影响,其中矿渣和硅灰能提高混凝土的抗压强度,粉煤灰和硅灰则可以提高混凝土的抗冻融性能。各因素的交互作用对混凝土各性能有不同程度的影响,其中矿渣和硅灰掺量的交互作用对28 d抗压强度影响显著,粉煤灰与硅灰掺量的交互作用对质量损失率影响显著,粉煤灰与矿渣掺量的交互作用对相对动弹性模量影响显著。基于目标响应值和响应优化,本试验条件下矿物掺合料的合理配合比为粉煤灰、矿渣和硅灰掺量分别为20%、15%和10%(质量分数)。
桥墩混凝土 BBD响应面法 矿物掺合料 抗压强度 冻融循环 质量损失率 相对动弹性模量 bridge pier concrete RSM-BBD mineral admixture compressive strength freeze-thaw cycle mass loss rate relative dynamic elastic modulus 
硅酸盐通报
2023, 42(7): 2401
王磊 1李花 1王永杰 1张彩虹 1,2,*[ ... ]吴培亨 1,2
作者单位
摘要
1 南京大学电子科学与工程学院,超导电子学研究所,江苏 南京 210023
2 紫金山实验室,江苏 南京 211111
提出了一种在超表面中嵌入二氧化钒(VO2)从而对太赫兹波进行动态调控的方法。VO2在68 ℃左右会发生绝缘体到金属的相变,导致其电导率发生4~5个数量级的显著变化。超表面由一个双开口金属谐振环阵列以及金属环开口处嵌入的VO2结构组成。仿真结果表明,通过改变VO2的电导率,太赫兹波可以实现高频与低频之间的谐振模式的切换。值得注意的是,这种模式转换不仅可以在实验中通过直接改变环境温度实现,还可以通过激光和强场太赫兹的泵浦完成。这种多样化的激励为该超表面在实际多场景应用中动态调控太赫兹波提供了参考。
光电子学 太赫兹 超材料与超表面 二氧化钒 激光泵浦 强场太赫兹 
中国激光
2023, 50(17): 1714015
张恒 1,2,3吕雪 1,2李华 3杭芹 1,2,*
作者单位
摘要
1 重庆邮电大学计算智能重庆市重点实验室,重庆 400065
2 重庆邮电大学计算机科学与技术学院,重庆 400065
3 中国科学院合肥物质科学研究院,安徽 合肥 230031
目前常用的光学诊断大部分局限于二维成像,而基于层析成像的三维重建方法受限于空间和时间分辨率,无法实现等离子体边界的三维实时重建。提出一种基于光学分层理论的光场反卷积算法,利用光场重聚焦特性,结合聚焦测距法和刃边法,建立了光场深度与现实深度的关系,计算出点扩散函数,实现了单相机零调焦情况下的等离子体边界重建。为验证所提方法的可行性,以火焰为成像对象进行实验,其结果表明所提方法能够去除火焰分层图像中的离焦模糊,复原分层图像的原始结构。
机器视觉 聚变等离子体 三维重建 光场重聚焦 光学分层成像 迭代反卷积 
光学学报
2023, 43(7): 0715001
作者单位
摘要
1 中国科学院西安光学精密机械研究所, 陕西 西安 710119
2 陕西理工大学机械工程学院, 陕西 汉中 723001
为了解决恒温条件下光学部件粘接用微厚胶层凝固应力无法定量获知的难题, 设计了一种微厚胶层恒温固化状态动态监测系统。首先通过微厚胶层恒温凝固应力产生机理及影响因素分析, 确定了微厚胶层恒温固化状态动态监测系统的工作原理, 制定了胶层固化状态监测系统的总体方案; 然后设计了各功能模块的关键部件结构, 对其支撑结构的刚度、挠度和形变进行详细计算与有限元分析, 并建立基于装配方向图的整机装配模型; 最后对所设计系统的性能进行实验验证。结果表明: 经过优化后的监测系统设计合理, 带45°支撑角的U型结构整体刚度较初选7型结构提高了84%, 使用该系统监测并获得了两种胶层固化阶段的状态特征和应力方向及数值, 应用效果良好。该研究为微厚胶层的固化原理提供了理论参考, 使恒温状态下微厚胶层固化状态实测成为可能。
微厚胶层 凝固应力 固化状态 监测系统 优化 slightly thick adhesive layer curing stress curing state monitoring systems optimization 
光学与光电技术
2023, 21(1): 37
刘涵 1,2李子平 1马旭红 1,2吴澍民 1,2[ ... ]黎华 1,2,*
作者单位
摘要
1 中国科学院上海微系统与信息技术研究所 中国科学院太赫兹固态技术重点实验室,上海 200050
2 中国科学院大学 材料与光电研究中心,北京 100049
3 上海科技大学 信息科学与技术学院,上海 201210
针对太赫兹量子级联激光器光频梳射频信号提取与传输存在的阻抗不匹配问题,设计并提出了一种输入阻抗为20 Ω、输出阻抗为50 Ω的渐变微带线结构,研究了该结构的准TEM模电场分布,并根据S参数建立了相应的LC等效电路模型分析其物理机理。实验中,将渐变微带线结构应用于太赫兹量子级联激光器光频梳射频信号提取与测试,以验证渐变微带线传输射频信号效果,成功测量得到太赫兹量子级联激光器重复频率,其线宽为3.7 kHz,信噪比达到60 dB,在注入电流为700~900 mA范围内重复频率表现为稳定的单模信号,测量得到的最大保持和幅度艾伦方差结果同样表现出重复频率的稳定性。实验结果表明,所设计的渐变微带线具有良好的阻抗匹配效果,能够实现对太赫兹量子级联激光器光频梳射频信号稳定的提取和传输。
太赫兹 量子级联激光器 光频梳 阻抗匹配 渐变微带线 Terahertz Quantum cascade laser Optical frequency comb Impedance matching Tapered microstrip line 
光子学报
2023, 52(1): 0114002
Wen Guan 1,2,3Ziping Li 1Shumin Wu 1,2Han Liu 1,2[ ... ]Hua Li 1,2,*
Author Affiliations
Abstract
1 Chinese Academy of Sciences, Shanghai Institute of Microsystem and Information Technology, Key Laboratory of Terahertz Solid State Technology, Shanghai, China
2 University of Chinese Academy of Sciences, Center of Materials Science and Optoelectronics Engineering, Beijing, China
3 ShanghaiTech University, School of Information Science and Technology, Shanghai, China
Stable operation is one of the most important requirements for a laser source for high-precision applications. Many efforts have been made to improve the stability of lasers by employing various techniques, e.g., electrical and/or optical injection and phase locking. However, these techniques normally involve complex experimental facilities. Therefore, an easy implementation of the stability evaluation of a laser is still challenging, especially for lasers emitting in the terahertz (THz) frequency range because the broadband photodetectors and mature locking techniques are limited. In this work, we propose a simple method, i.e., relative phase locking, to quickly evaluate the stability of THz lasers without a need of a THz local oscillator. The THz laser system consists of a THz quantum cascade laser (QCL) frequency comb and a single-mode QCL. Using the single-mode laser as a fast detector, heterodyne signals resulting from the beating between the single-mode laser and the comb laser are obtained. One of the heterodyne beating signals is selected and sent to a phase-locked loop (PLL) for implementing the relative phase locking. Two kinds of locks are performed by feeding the output error signal of the PLL, either to the comb laser or to the single-mode laser. By analyzing the current change and the corresponding frequency change of the PLL-controlled QCL in each phase-locking condition, we, in principle, are able to experimentally compare the stability of the emission frequency of the single-mode QCL (fs) and the carrier envelope offset frequency (fCEO) of the QCL comb. The experimental results reveal that the QCL comb with the repetition frequency injection locked demonstrates much higher stability than the single-mode laser. The work provides a simple heterodyne scheme for understanding the stability of THz lasers, which paves the way for the further locking of the lasers and their high-precision applications in the THz frequency range.
terahertz quantum cascade laser frequency comb phase lock 
Advanced Photonics Nexus
2023, 2(2): 026006
Author Affiliations
Abstract
1 Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2 Department of Physics and Engineering Physics, Tulane University, New Orleans, USA
Two-dimensional (2D) semiconductors have captured broad interest as light emitters, due to their unique excitonic effects. These layer-blocks can be integrated through van der Waals assembly,i.e., fabricating homo- or heterojunctions, which show novel emission properties caused by interface engineering. In this review, we will first give an overview of the basic strategies that have been employed in interface engineering, including changing components, adjusting interlayer gap, and tuning twist angle. By modifying the interfacial factors, novel emission properties of emerging excitons are unveiled and discussed. Generally, well-tailored interfacial energy transfer and charge transfer within a 2D heterostructure cause static modulation of the brightness of intralayer excitons. As a special case, dynamically correlated dual-color emission in weakly-coupled bilayers will be introduced, which originates from intermittent interlayer charge transfer. For homobilayers and type Ⅱ heterobilayers, interlayer excitons with electrons and holes residing in neighboring layers are another important topic in this review. Moreover, the overlap of two crystal lattices forms moiré patterns with a relatively large period, taking effect on intralayer and interlayer excitons. Particularly, theoretical and experimental progresses on spatially modulated moiré excitons with ultra-sharp linewidth and quantum emission properties will be highlighted. Moiré quantum emitter provides uniform and integratable arrays of single photon emitters that are previously inaccessible, which is essential in quantum many-body simulation and quantum information processing. Benefiting from the optically addressable spin and valley indices, 2D heterostructures have become an indispensable platform for investigating exciton physics, designing and integrating novel concept emitters.Two-dimensional (2D) semiconductors have captured broad interest as light emitters, due to their unique excitonic effects. These layer-blocks can be integrated through van der Waals assembly,i.e., fabricating homo- or heterojunctions, which show novel emission properties caused by interface engineering. In this review, we will first give an overview of the basic strategies that have been employed in interface engineering, including changing components, adjusting interlayer gap, and tuning twist angle. By modifying the interfacial factors, novel emission properties of emerging excitons are unveiled and discussed. Generally, well-tailored interfacial energy transfer and charge transfer within a 2D heterostructure cause static modulation of the brightness of intralayer excitons. As a special case, dynamically correlated dual-color emission in weakly-coupled bilayers will be introduced, which originates from intermittent interlayer charge transfer. For homobilayers and type Ⅱ heterobilayers, interlayer excitons with electrons and holes residing in neighboring layers are another important topic in this review. Moreover, the overlap of two crystal lattices forms moiré patterns with a relatively large period, taking effect on intralayer and interlayer excitons. Particularly, theoretical and experimental progresses on spatially modulated moiré excitons with ultra-sharp linewidth and quantum emission properties will be highlighted. Moiré quantum emitter provides uniform and integratable arrays of single photon emitters that are previously inaccessible, which is essential in quantum many-body simulation and quantum information processing. Benefiting from the optically addressable spin and valley indices, 2D heterostructures have become an indispensable platform for investigating exciton physics, designing and integrating novel concept emitters.
van der Waals assembly interface interaction interlayer gap twist angle intralayer and interlayer excitons moiré excitons 
Journal of Semiconductors
2023, 44(1): 011001
杨思嘉 1,2李子平 1,2廖小瑜 1,2王晨捷 1,2[ ... ]曹俊诚 1,2,**
作者单位
摘要
1 中国科学院上海微系统与信息技术研究所 太赫兹固态技术实验室,上海 200050
2 中国科学院大学 光电子学材料研究中心,北京 100083
太赫兹量子级联激光器(THz QCL)双光梳在光谱检测、测距、成像等领域具有重要应用。双光梳信号严重依赖THz耦合光功率。利用THz QCL激射光为线偏振光的特性,在双光梳光路上插入线偏振片,通过旋转偏振片以达到对THz光强进行调节的作用。系统研究了THz QCL双光梳谱和功率与偏振角度的依赖关系,为实现高稳定THz双光梳光源与应用奠定基础。
太赫兹 量子级联激光器 双光梳 偏振 terahertz quantum cascade laser dual-comb polarization 
红外与毫米波学报
2022, 41(5): 825

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